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Showing posts with label Alkenes. Show all posts
Showing posts with label Alkenes. Show all posts

Thursday 10 February 2022

Rules for Nomenclature and Alkenes: ( IUPAC)

 ALKENES:

Alkenes are unsaturated hydrocarbons which contain a carbon-carbon double bond. 

They can be represented by the general formula CnH2n. 

Why alkenes are called olefins?

They are also known as 'olefins', derived from Latin word 'oleum' meaning 'oil' and 'ficare' meaning 'to form', because their lower members form oily layer on treatment with chlorine and bromine.

Rules for Nomenclature and Alkenes: ( IUPAC)

Following are the some rules 

1. Select  longest continuous chain of carbon          atom as a parent chain containing double bond.

2. Name of compound must end on ene .

      E.g ethene propene etc

3.Give double bond  least possible number.

4.Substiutnt name is always written before              parent name.

5.Position of double bond must be mentioned.

6.Position of substituent must be mentioned         before name

7.If more then one similar type of substituents are present we will use the term di For 2 Tri for 3

 Tetra  for 4

8.If different type of substituents are present          we  will follow alphabatical order .

9.If more then one double bonds are present we will use the term diene for 2 double bonds and triene for 3 double bonds

Examples      

            1      2      3      4     5     6                                         CH3-CH=CH-CH2-CH2-CH3  2- Hexene


                 CH3                                                                               |                                                                    CH3-CH=C-CH-CH2-CH3 

          3-Methyl-2-Hexene

 1      2      3      4     5     6

CH3-CH=CH-CH=CH-CH3  2,4-Hexadiene



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